790 research outputs found
Close-circuit domain quadruplets in BaTiO nanorods embedded in SrTiO film
Cylindrical BaTiO3 nanorods embedded in (100)-oriented SrTiO3 epitaxial film
in a brush-like configuration are investigated in the framework of the
Ginzburg-Landau-Devonshire model. It is shown that strain compatibility at
BaTiO3/SrTiO3 interfaces keeps BaTiO3 nanorods in the rhombohedral phase even
at room temperature. Depolarization field at the BaTiO3/SrTiO3 interfaces is
reduced by an emission of the 109-degree or 71-degree domain boundaries. In
case of nanorods of about 10-80 nm diameter, the ferroelectric domains are
found to form a quadruplet with a robust flux-closure arrangement of the
in-plane components of the spontaneous polarization. The out-of-plane
components of the polarization are either balanced or oriented up or down along
the nanorod axis. Switching of the out-of-plane polarization with coercive
field of about V/m occurs as a collapse of a 71-degree cylindrical
domain boundary formed at the curved circumference surface of the nanorod. The
remnant domain quadruplet configuration is chiral, with the macroscopic
symmetry. More complex stable domain configurations with coexisting clockwise
and anticlockwise quadruplets contain interesting arrangement of strongly
curved 71-degree boundaries.Comment: Erratta - corrected error in Fig.
N-body U and K matrix program
Computer program was devised to compute free-fall trajectories of satellites, allowing for injection errors and midcourse velocity perturbations. Program consists of trajectory perturbing program and N-body integrating conic program which can also be used as 2-body patch conic program
Shadow constraint program
Shadow constraint program computations of trajectories intersection with shadow cone for use in Centaur projec
Uniaxial-stress induced phase transitions in [001]c-poled 0.955Pb(Zn1/3Nb2/3)O3-0.045PbTiO3
First-order, rhombohedral to orthorhombic, stress-induced phase transitions
have been evidenced by bulk charge-stress measurements and X-ray diffraction
derived lattice strain measurements in [001]c-poled PZN-4.5PT. The transitions
are induced by uniaxial, compressive loads applied either along or
perpendicular to the poling direction. In each case, they occur via rotation of
the polar vector in the Cm monoclinic plane and the induced lattice strain is
hysteretic yet reversible. Although no depoling is observed in the transverse
mode, net depolarization is observed under longitudinal stress which is
important for the use of [001]c-poled PZN-PT and PMN-PT single crystals in
Tonpilz-type underwater projectors.Comment: To be published in Applied Physics Letters, 16 pages, 3 figure
Central mode and soft mode behavior in PbMg1/Nb2/3O3 relaxor ferroelectric
The relaxor ferroelectric PbMg1/Nb2/3O3 was investigated by means of
broad-band dielectric and Fourier Transform Infrared (FTIR) transmission
spectroscopy in the frequency range from 1 MHz to 15 THz at temperatures
between 20 and 900 K using PMN films on infrared transparent sapphire
substrates. While thin film relaxors display reduced dielectric permittivity at
low frequencies, their high frequency intrinsic or lattice response is shown to
be the same as single crystal/ceramic specemins. It was observed that in
contrast to the results of inelastic neutron scattering, the optic soft mode
was underdamped at all temperatures. On heating, the TO1 soft phonon followed
the Cochran law with an extrapolated critical temperature equal to the Burns
temperature of 670 K and softened down to 50 cm-1. Above 450 K the soft mode
frequency leveled off and slightly increased above the Burns temperature. A
central mode, describing the dynamics of polar nanoclusters appeared below the
Burns temperature at frequencies near the optic soft mode and dramatically
slowed down below 1 MHz on cooling below room temperature. It broadened on
cooling, giving rise to frequency independent losses in microwave and lower
frequency range below the freezing temperature of 200 K. In addition, a new
heavily damped mode appeared in the FTIR spectra below the soft mode frequency
at room temperature and below. The origin of this mode as well as the
discrepancy between the soft mode damping in neutron and infrared spectra is
discussed.Comment: 7 pages with 7 figures, submitted to Phys. Rev.
Effect of mechanical loading on the tuning of acoustic resonances in Ba x Sr1− x TiO3 thin films
The effect of mechanical loading on the tuning performance of a tunable Thin Film Bulk Acoustic Wave Resonator (TFBAR) based on a Ba0.3Sr0.7TiO3 (BST) thin film has been investigated experimentally and theoretically. A membrane-type TFBAR was fabricated by means of micromachining. The mechanical load on the device was increased stepwise by evaporating SiO2 on the backside of the membrane. The device was electrically characterized after each evaporation step and the results were compared to those obtained from modeling. The device with the smallest mechanical load exhibited a tuning of − 2.4% and − 0.6% for the resonance and antiresonance frequencies at a dc electric field of 615kV/cm, respectively. With increasing mechanical load a decrease in the tuning performance was observed. This decrease was rather weak if the thickness of the mechanical load was smaller or comparable to the thickness of the active BST film. If the thickness of the mechanical load was larger than the thickness of the active BST layer, a significant reduction in the tuning performance was observed. The weaker tuning of the antiresonance frequency was due to a reduced tuning of the sound velocity of the BST layer with increasing dc bias. The resonance frequency showed a reduced tuning due to a decrease in the effective electromechanical coupling factor of the device with increasing mechanical load. With the help of the modeling we could de-embed the intrinsic tuning performance of a single, non-loaded BST thin film. We show that the tuning performance of the device with the smallest mechanical load we fabricated is close to the intrinsic tuning characteristics of the BST laye
Piezoelectric anisotropy: Enhanced piezoelectric response along nonpolar directions in perovskite crystals
This paper discusses the mechanisms that can contribute to the enhanced longitudinal piezoelectric effect along nonpolar directions in perovskite crystals, such as BaTiO3, PbTiO3, KNbO3, Pb(Mg1/3Nb2/3)O3-PbTiO3 and Pb(Zn1/2Nb2/3)O3-PbTiO3. Piezoelectric anisotropy is discussed in relation to temperature induced phase transitions, compositional variation in solid solutions with morphotropic phase boundaries, applied electric fields, the domain wall structure and domain wall displacemen
Fabrication and structural analysis of ZnO coated fiber optic phase modulators
Fiber optic modulators were fabricated by coating optical fibers with electrode and piezoelectric ZnO layers. The techniques of piezoelectric fiber optic modulator (PFOM) fabrication are presented, and the microstructure and crystallographic texture of the coatings are analyzed. In order to produce thick (approximately 5 μm) ZnO coatings, it was necessary to study the reactive dc magnetron sputtering process in O2/Ar gas mixtures under conditions close to the transition between an oxidized and nonoxidized Zn target surface. In situ quartz crystal microbalance measurements of the deposition rate revealed thee distinct regions in the deposition rate (R) vs oxygen partial pressure behavior, at constant total pressure, for sputtering under conditions that provided an oxidized Zn target surface. Additionally, a transition between oxygen and argon dominated sputtering as observed by varying the sputtering pressure while maintaining a constant The transition between oxygen and argon dominated sputtering influences R to varying extents within the three R vs regions for an oxidized target surface. Correlations among the cathode current and voltage, deposition rate, and gas flow rate are presented to give a better understanding of the reactive sputtering processes occurring at the oxidized Zn target surface. Sputtering conditions optimized for a high ZnO deposition rate were used to produce 〈001〉 radially oriented ZnO fiber coatings for PFOM devices that can produce optical phase shifts as large as 0.38 rad/
Influence of substrate bias on the structural and dielectrical properties of magnetron-sputtered BaxSr1-xTiO3 thin films
The application of a substrate bias during rf magnetron sputtering alters the
crystalline structure, grain morphology, lattice strain and composition of
BaxSr1-xTiO3 thin films. As a result, the dielectric properties of
Pt/BaxSr1-xTiO3/Pt parallel-plate capacitors change significantly. With
increasing substrate bias we observe a clear shift of the ferroelectric to
paraelectric phase transition towards higher temperature, an increase of the
dielectric permittivity and tunability at room temperature, and a deterioration
of the dielectric loss. To a large extent these changes correlate to a gradual
increase of the tensile in-plane film strain with substrate bias and an abrupt
change in film composition.Comment: 24 pages, 8 figures, submitted to Ferroelectric
Landau thermodynamic potential for BaTiO_3
In the paper, the description of the dielectric and ferroelectric properties
of BaTiO_3 single crystals using Landau thermodynamic potential is addressed.
Our results suggest that when using the sixth-power free energy expansion of
the thermodynamic potential, remarkably different values of the fourth-power
coefficient, \beta (the coefficient of P^4_i terms), are required to adequately
reproduce the nonlinear dielectric behavior of the paraelectric phase and the
electric field induced ferroelectric phase, respectively. In contrast, the
eighth-power expansion with a common set of coefficients enables a good
description for both phases at the same time. These features, together with the
data available in literature, strongly attest to the necessity of the
eighth-power terms in Landau thermodynamic potential of BaTiO_3. In addition,
the fourth-power coefficients, \beta and \xi (the coefficient of P^2_i P^2_j
terms), were evaluated from the nonlinear dielectric responses along [001],
[011], and [111] orientations in the paraelectric phase. Appreciable
temperature dependence was evidenced for both coefficients above T_C. Further
analysis on the linear dielectric response of the single domain crystal in the
tetragonal phase demonstrated that temperature dependent anharmonic
coefficients are also necessary for an adequate description of the dielectric
behavior in the ferroelectric phase. As a consequence, an eighth-power
thermodynamic potential, with some of the anharmonic coefficients being
temperature dependent, was proposed and compared with the existing potentials.
In general, the potential proposed in this work exhibits a higher quality in
reproducing the dielectric and ferroelectric properties of this prototypic
ferroelectric substance.Comment: 7 figures, 5 table
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